XAFS Investigation of Chromium(Ⅲ)-Amino Acid-Nicotinic Acid Mixed Ligand Complexes

  • Chromium(Ⅲ) can form mixed ligand complexes with amino-acids(glycine,glutamic acid,cysteine et al) and nicotinic acid.Chromium(Ⅲ) has been recognized as a trace element essential for both animal and human nutrition.The characteristics of local structures around Cr in chromium(Ⅲ)-amino acid-nicotinic acid mixed ligand complexes are investigated by EXAFS.The structural parameters of the nearest neighbors around Cr are obtained by simulating the first coordination peak in RSF.
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  • [1] Toepler E W, Merla W, Polallsky M M el al. J. Agr. Food Chem. ,1977, 25(1) :162-1662 Cooper J A, Anderson B F, Ruckley P D et al. lnorganica Chimica Acta. , 1984a,91:1-93 Cooper J A , Blackwell L F , Buckley P D. Chromium ( 111) Complexes and Their Relationship to the Glucose Tolerance Factor. Part TI.Struclurea and Biological Aclivily of Amiuo acid Complexes. Inorganica Chiniica Acta. , 1984b,92:23-314 Cooper J A, Haylock S J , Rlackwell L F et al. An Investigation byIon-Exchanged Chronialography of a Chromium, Amino Acid aud Nicolinic Acid Mixlure. Inorganica Chiniica Acta. , 1985,106 :223-2275 DAT G Z. YAN B Z. Studies of the Composition and Stability of Chroniiuni( 111 ) -Amino Acid-Nicolinic Acid Mixed Ligand Complexes,West China Center of Medical Science, 1986, 17 ( 1 ) : 33-39 ( in Chinese)(戴光智,严保珍.铬(III)一氨基酸一烟酸混配络合物组成及稳定性的研究,华西保科大学学报,1986, 17(1),33-39)6 MA L D, YANG J F. An Introduction to Synchrotron Radiation Applicalion.Shanghai : Fudau Universily Press, 2001 , 2 : 149-151 (in Chinese)(马礼敦,杨福家.同步辐射应用概论,上海:复旦大学出版社,2001,2:149-151)7 Rehr J J , Albers B C. Reviews of Modem Physics, 2000, 72 ( 3 ) :621 -6548 WANC Q W, LIU W H. Theory and Applicatiou of X-ray Ahsorption Fine Struclure. Beijing : Science Press, 1994 ( in Chinese)(王其武,刘文汉.x射线吸收精细结构及其应用.北京:科学出版社,1994)9 Frauk E , Huggins, Mohaniniad Najih. Fuel, 1999, 78 :233-24210 Ronald R , Patterson, Scott Fendorf. Environmental Science Technology, 1997, 31 (7 ) :2039-204411 Norman D, Garg K B. Solid State Commun, 1995, 56 :89512 Sipr 0. J. Phys. Condens, 1992,4: 938913 Crioni M, Cayayk M T. Phys. Rev. , 1989, B39 :4886
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HU Rong, LIU Jing, M.I.Abbas, HU Tian-Dou, Xie Ya-Ning, FENG Wei-Yue, CHAI Zhi-Fang and Wu Zi-Yu. XAFS Investigation of Chromium(Ⅲ)-Amino Acid-Nicotinic Acid Mixed Ligand Complexes[J]. Chinese Physics C, 2003, 27(S1): 15-18.
HU Rong, LIU Jing, M.I.Abbas, HU Tian-Dou, Xie Ya-Ning, FENG Wei-Yue, CHAI Zhi-Fang and Wu Zi-Yu. XAFS Investigation of Chromium(Ⅲ)-Amino Acid-Nicotinic Acid Mixed Ligand Complexes[J]. Chinese Physics C, 2003, 27(S1): 15-18. shu
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Received: 2003-11-21
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XAFS Investigation of Chromium(Ⅲ)-Amino Acid-Nicotinic Acid Mixed Ligand Complexes

    Corresponding author: HU Rong,
  • Institute of High Energy Physics,Chinese Academy of Sciences,Beijing 100039,China

Abstract: Chromium(Ⅲ) can form mixed ligand complexes with amino-acids(glycine,glutamic acid,cysteine et al) and nicotinic acid.Chromium(Ⅲ) has been recognized as a trace element essential for both animal and human nutrition.The characteristics of local structures around Cr in chromium(Ⅲ)-amino acid-nicotinic acid mixed ligand complexes are investigated by EXAFS.The structural parameters of the nearest neighbors around Cr are obtained by simulating the first coordination peak in RSF.

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