Evaluation of Structural Parameters in Semicrystalline Polymer Three-Phase Systems by Small-Angle X-Ray Scattering

ZHAO Hui; WU Zhong-Hua; GUO Mei-Fang; DONG Bao-Zhong

Chinese Physics C> 2003, Vol. 27> Issue(11) : 1034-1038

Evaluation of Structural Parameters in Semicrystalline Polymer Three-Phase Systems by Small-Angle X-Ray Scattering

Beijing Synchrotron Radiation Laboratory, Institute of High Energy Physics, CAS, Beijing 100039, China2 Department of Physics, Anshan Normal College, Anshan 114005, China3 Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation, Beijing 100013, China

Abstract
HTML
Reference
Related

PDF

Abstract：
The structural parameters in a semicrystalline polymer three-phase system have been evaluated using small angle X-ray scattering technique. The crystallinity and the lamellar thickness are not consistent with those in two-phase system. The analysis of some semicrystalline polymer samples indicates that the Bragg long period approaches to the sum of the correlation function long period and the thickness of the transition layer. It is also consistent with the conclusion that the interphase layers exist in semicrystalline polymers.

References

[1]

Porod G. Kolloid–Z., 1951, 124:83–114 2 Debye P, Bueche A M. J. Appl. Phys., 1949, 20:518–5253 Tsvankin D Ya, Zubov Yu A, Kitaigorodskii A I. J. Polymer Sci., 1968, C6:4081–4091 4 Vonk C G. J. Appl. Cryst., 1973, 6: 81–865 Strobl G R, Schneider M J. Polym. Sci. Polym. Phys. Ed., 1980, 18:1343–1359 6 Flory P J, Yoon D Y, Dill K A. Macromolecules, 1984, 17:8627 Yoon D Y, Flory P J. Mcromolecules, 1984,17:868–871 8 Hahn B R, Herrmann–schnherr O, Wendorff J H. Polymer, 1987, 28:201–2089 Vonk C G, Pijpers A P. J. Polym. Sci. Polym. Phys. Ed., 1985, 23: 2517–253710 ZHANG Hong–Fang, YIN Jing–Hua. Makromol. Chem., 1990, 191: 375–38011 ZHANG Hong–Fang et al. Macromol. Chem. Phys., 1996,197(2) : 553–562 12 ZHAO Hui et al. HEP NP, 2001, Supp: 81–84(in Chinese)(赵辉等.高能物理与核物理,2001,增刊:81–84) 13 Caulfield D, Ullman R. J. Appl. Phys., 1962, 33:1737–1740 14 Guinier A, Fournet G. Small–Angle Scattering of X–Ray. New York: Wiley, 1955． 24–28

[1]	HE Wei , ZHAO Hong-Wei . Structure Analysis of the SECRAL Superconducting Magnet System. Chinese Physics C, 2007, 31(S1): 31-36.
[2]	DU Ying-Chao , HUANG Wen-Hui , TANG Chuan-Xiang , HUA Jian-Fei , CHENG Cheng , DU Tai-Bin , XIA Bing , He Xiao-Zhong , DU Qiang , ZHENG Shu-Xin , CHEN Huai-Bi , LIN Yu-Zheng . Preliminary Experiments of Thomson Scattering X-ray Source: Measurements of Electron beam's Parameters and Their Influence on the X-ray Performance. Chinese Physics C, 2006, 30(S1): 84-86.
[3]	GU Peng-Da , GEN Zhe-Qiao , CUI Yan-Yan , PEI Guo-Xi , WANG Shu-Hong . Design Studies of RF Phasing System for BEPCII Linac. Chinese Physics C, 2005, 29(3): 316-320.
[4]	YU Zong-Qiang , ZHOU Hua-Shi , GAO Shu-Qi . Coherent X-Ray Scatter for Identifiction of Explosives. Chinese Physics C, 2005, 29(6): 619-622.
[5]	SHEN Da-Wa , YU Hui , WU Zong-Hua , HUANG Yong . The Morphology of CDA-g-PMMA Copolymers in Solution Studied by SR-SAXS. Chinese Physics C, 2005, 29(S1): 8-11.
[6]	HU Shu-Xin , LI Da-Peng , MAI Zhen-Hong , LI Ming . Small Angle X-ray Scattering Study of the Influence of Temperature on the Structure of DNA/Lipid Complexes. Chinese Physics C, 2005, 29(S1): 4-7.
[7]	WU Xiao-Shan , TAN Wei-Shi , JIANG Shu-Sheng , WU Zhong-Hua , DING Yong-Fan , . Microstructures of Ge/Si Superlattices Growtn at Low Temperature. Chinese Physics C, 2003, 27(8): 739-743.
[8]	HONG Xin-Guo , DU Lu-Chao , YE Man-Ping , WENG Yu-Xiang , LI Ming . In Situ Synchrotron Small Angle X-ray Scattering Studies of TiO₂ Colloid at Elevated Temperature. Chinese Physics C, 2003, 27(S1): 63-66.
[9]	HU Shu-Xin , LI Xiu-Hong , WU Lan-Sheng , JIA Quan-Jie , MAI Zhen-Hong , LI Ming . X-ray scattering of polymerizable lipid multilayers aligned at liquid-solid interfaces. Chinese Physics C, 2003, 27(S1): 53-56.
[10]	ZHAO Hui , LI Zhi-Hong , DONG Bao-Zhong , RONG Li-Xia , WANG Jun . Preliminary Transformation on Experimental Data of Small Angle X-Ray Scattering. Chinese Physics C, 2001, 25(S1): 81-84.
[11]	Pan Feng , Luo Yanan , Yu Shenqi . q-Deformation of Three-Parameter Wu-Zeng Formula. Chinese Physics C, 1998, 22(1): 61-70.
[12]	Zhao Peiying , Wu Jimin . Phase Structure of U(1) Lattice Gauge Theory by Variational Study with Independent Plaquette Effective Action. Chinese Physics C, 1996, 20(2): 124-130.
[13]	Dong Baozhong , Sheng Wenjun , Li Guangcheng , Zhang Zhijie . Small Angle Scattering Station of BEPC Synchrotron Radiation Laboratory. Chinese Physics C, 1995, 19(3): 284-288.
[14]	Ruan Wenying , Bac Chengguang . The Effect of Symmetry on The Structures of Three-Body Systems. Chinese Physics C, 1994, 18(1): 74-80.
[15]	LU Gong-Ru , WAN Ling-De . Analyses of Complementarity and Critical Coupling Higgs Phase. Chinese Physics C, 1991, 15(1): 29-37.
[16]	LIU MAO-SAN , CHEN REN-HUAI , WU WEN-TAI , LI SHU-ZHEN . ON THE ANALYSIS OF SEGMENTED RING PERMANENT MAGNET MULTIPOLE FIELDS. Chinese Physics C, 1981, 5(1): 127-129.
[17]	ZHANG YU-SHUN , LI YANG-GUO , WANG WEI-WEI , CHEN XIAO-TIAN , RUAN TU-NAN . THE SU(6) “UNITARY ENERGY BAND” STRUCTURE IN THE TRIBARYON SYSTEM. Chinese Physics C, 1981, 5(5): 521-530.
[18]	LIU MAO-SAN , CHEN REN-HUAI , WU WEN-TAI , LI SHU-ZHEN . ON THE ANALYSIS OF SEGMENTED RING OF PERMANENT MAGNET MULTIPOLE FIELDS. Chinese Physics C, 1981, 5(4): 452-457.
[19]	Liu Mao-san , Chen Ren-huai , Wu Wen-tai , Li Shu-zhen . PLANAR MULTIPOLE FIELD OF A PERMANENT MAGNET SYSTEM WITH MULTI-SEGMENTED RING STRUCTURE. Chinese Physics C, 1980, 4(6): 774-777.
[20]	Wei Kai-yu . THE PARAMETERS AND ELECTRICAL TOLERANCE ANALYSIS FOR THE SINGLE BUNCHER SYSTEMS. Chinese Physics C, 1980, 4(6): 706-714.

Access

Get Citation

ZHAO Hui, WU Zhong-Hua, GUO Mei-Fang and DONG Bao-Zhong. Evaluation of Structural Parameters in Semicrystalline Polymer Three-Phase Systems by Small-Angle X-Ray Scattering[J]. Chinese Physics C, 2003, 27(11): 1034-1038.

RIS(for EndNote,Reference Manager,ProCite)

BibTex

Txt

Milestone

Received: 2003-03-24
Revised: 1900-01-01

Article Metric

Article Views(2614)
PDF Downloads(559)
Cited by(0)

Policy on re-use

To reuse of subscription content published by CPC, the users need to request permission from CPC, unless the content was published under an Open Access license which automatically permits that type of reuse.

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Evaluation of Structural Parameters in Semicrystalline Polymer Three-Phase Systems by Small-Angle X-Ray Scattering

Corresponding author: ZHAO Hui,

Beijing Synchrotron Radiation Laboratory, Institute of High Energy Physics, CAS, Beijing 100039, China2 Department of Physics, Anshan Normal College, Anshan 114005, China3 Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation, Beijing 100013, China

Received Date: 2003-03-24

Accepted Date: 1900-01-01

Available Online: 2003-11-05

Abstract: The structural parameters in a semicrystalline polymer three-phase system have been evaluated using small angle X-ray scattering technique. The crystallinity and the lamellar thickness are not consistent with those in two-phase system. The analysis of some semicrystalline polymer samples indicates that the Bragg long period approaches to the sum of the correlation function long period and the thickness of the transition layer. It is also consistent with the conclusion that the interphase layers exist in semicrystalline polymers.

HTML

Reference (1)

Evaluation of Structural Parameters in Semicrystalline Polymer Three-Phase Systems by Small-Angle X-Ray Scattering

Abstract：

References

Access

Article Metrics

Metrics

通讯作者: 陈斌, bchen63@163.com

Email This Article